Sentinel SB Dampproofing	
Safety Data Sheet	
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations	
Revision Date: 01/28/2022	Date of Issue: 09/10/2015	Version: 2.0	

SECTION 1: IDENTIFICATION
Product Identifier
	Product Form:  Solvent
	Product Name:  Sentinel SB Dampproofing
	Name, Address, and Telephone of the Responsible Party
Manufacturer		
GMX, Inc.		
P.O. Box 743		
Matthews, NC 28106		
	Emergency Telephone Number
	Emergency Number:  1-800-424-9300 (CHEMTREC)
  Main Switch Board: (704) 334-8222

SECTION 2: HAZARDS IDENTIFICATION

Classification of the Substance or Mixture Classification (GHS-US)
H226 - Flam. Liq. 3
H304 - Asp. Tox. 1	
H319 – Eye irrit. 2A
H340 - Muta. 1B
H350 - Carc. 1B	
H351 – Carc. 2
H400 - Aquatic Acute 1
H411 - Aquatic Chronic 2	

Label Elements

GHS-US Labeling
Hazard Pictograms (GHS-US)	:	
	
Signal Word (GHS-US)	:	Danger	
Hazard Statements (GHS-US)	:	H226 - Flammable liquid and vapour.
H304 - May be fatal if swallowed and enters airways	
		H319 – Causes serious eye irritation.
H340 - May cause genetic defects by route of exposure if conclusively proven that no other route applies.
H350 - May cause cancer by route of exposure if conclusively proven that no other route applies 	
		H351 – Suspected of causing cancer by route of exposure if conclusively proven that no other route exposes.
H400 - Very toxic to aquatic life.
H411 - Toxic to aquatic life with long lasting effects.	
Precautionary Statements (GHS-US)	:	P201 – Obtain special instructions before use.	
		P202 – Do not handle until all safety precautions have been read and understood.	
		P210 – Keep away from heat.	
		P233 – Keep container tightly closed.	
		P240 – Ground/bond container and receiving equipment.	
		P241 – Use explosion-proof electrical/ventilating/equipment.	
		P242 – Use only non-sparking tools.	
		P243 – Take precautionary measures against static discharge.	
		P264 – Wash face, hands, and any exposed skin thoroughly after handling.
P273 - Avoid release to the environment.	
		P280 – Wear protective gloves/protective clothing/eye protection/face protection.	
		P281 – Use personal protective equipment as required.
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.	
		P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P313 – If exposed or concerned: Get medical advice/attention.	
		P337+P313 – if eye irritation persists: Get medical attention/advice.
P370 + P378 - In case of fire: Use extinguishing media for extinction.
P391 - Collect spillage.
P403 + P235 - Store in a well-ventilated place. Keep cool.	
		P405 – Store locked up.	
		P501 – Dispose of contents/container according to local, regional, national, and international regulations.	
Other Hazards 
Other Hazards Not Contributing to the Classification: Not available.

Unknown Acute Toxicity (GHS-US)

No data available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Not available
Mixture
Name	Product identifier	% (w/w)	Classification (GHS-US)	
Asphalt	CAS No (8052-42-4)	60-100	H225 - Flam. Liq. 2
H319 – Eye Irrit. 2A
H351 – Carc. 2	
Stoddard Solvent	CAS No (8052-41-3)	10-30	H226 - Flam. Liq. 3
H340 - Muta. 1B
H350 - Carc. 1B
H304 - Asp. Tox. 1
H400 - Aquatic Acute 1
H411 - Aquatic Chronic 2	
SECTION 4: FIRST AID MEASURES

Description of First Aid Measures
First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). IF exposed or concerned: Get medical advice/attention.
First-aid Measures After Inhalation: Move to fresh air. Oxygen or artificial respiration if needed. If symptoms persist, call a physician.
First-aid Measures After Skin Contact: Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. Remove and wash contaminated clothing before re-use. If skin irritation persists, call a physician.
First-aid Measures After Eye Contact: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

First-aid Measures After Ingestion: Call a physician or Poison Control Center immediately. Never give anything by mouth to an unconscious person. Do not induce vomiting without medical advice.

SECTION 5: FIRE-FIGHTING MEASURES
Extinguishing Media
Suitable Extinguishing Media: Carbon dioxide (CO2). Foam. Dry powder. Dry chemical.
Unsuitable Extinguishing Media: Do not use a solid water stream as it may scatter and spread fire.
Special Hazards Arising From the Substance or Mixture
No information available
Advice for Firefighters
Firefighting Instructions: Exercise caution when fighting any chemical fire.
Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
Reference to Other Sections
Refer to section 9 for flammability properties.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Evacuate personnel to safe areas.
For Non-emergency Personnel
Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel.
For Emergency Responders

Protective Equipment: Equip cleanup crew with proper protection.
Emergency Procedures: Ventilate area.
Environmental Precautions
Prevent further leakage or spillage if safe to do so. Prevent product from entering drains.
Methods and Material for Containment and Cleaning Up
For Containment and Clean Up: Dike with inert absorbent material (e.g. dry sand or earth). Take precautionary measures against static discharges. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. Keep in suitable and closed containers for disposal. Dispose of as common waste.
Reference to Other Sections
See heading 8, Exposure Controls and Personal Protection.
SECTION 7: HANDLING AND STORAGE
Precautions for Safe Handling
Avoid contact with skin and eyes. Ensure adequate ventilation.
Conditions for Safe Storage, Including Any Incompatibilities
Storage Conditions: Keep container tightly closed. Keep in properly labeled containers. Keep out of the reach of children.

Incompatible Materials: Not available.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Control Parameters 

Chemical Name 	ACGIH TLV	OSHA PEL	Ontario TWAEV	Mexico 	
Petroleum Asphalt	TWA: 0.5 mg/m3		TWA: 0.5 mg/m3	STEL: 10 mg/m3 
TWA: 5 mg/m3	
Stoddard Solvent	TWA: 100 ppm	TWA: 2900 mg/m3 
TWA: 500 ppm	TWA: 525 mg/m3	STEL: 200 ppm 
STEL: 1050 mg/m3 
TWA: 523 mg/m3 
TWA: 100 ppm	

Chemical Name 	NIOSH IDLH 	
Stoddard Solvent	20000 mg/m3	

  Exposure Controls
Appropriate Engineering Controls: Do not allow ventilation equipment to draw material odors indoors.
Personal Protective Equipment: Gloves. Protective clothing. Protective goggles. 

  

Hand Protection: Protective gloves.
Eye Protection: Chemical goggles or safety glasses.
Skin and Body Protection: Wear suitable protective clothing.
Respiratory Protection: If exposure limits are exceeded or irritation is experienced, NIOSH approved respiratory protection should be worn.
Hygiene Measures: Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing before re-use. Handle in accordance with good industrial hygiene and safety practice.
  Other Information: When using, do not eat, drink, or smoke.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on Basic Physical and Chemical Properties 
Physical State	:	Liquid	
Appearance	:	Brown/black liquid	
Odor	:	Slight odor	
Odor Threshold	:	Not available	
pH	:	9.5-11.5	
Relative Evaporation Rate (butyl acetate = 1)	:	Not available	
Melting Point	:	Not available	
Freezing Point	:	32°F/ 0°C	
Boiling Point	:	212°F / 100°C	
Flash Point	:	>400°F (>204°C)	
Auto-ignition Temperature	: 	> 700°F / > 371°C	
Decomposition Temperature	:	Not available	
Flammability (solid, gas)	:	Not available	
Lower Flammable Limit	:	Not available	
Upper Flammable Limit	:	Not available	
Vapor Pressure	:	Not available	
Relative Vapor Density at 68°F (20°C)	:	> 1 (Air = 1)	
Relative Density	:	Not available	
Specific Gravity	:	>1.0	
Solubility	:	Partly miscible	
Partition coefficient: n-octanol/water	:	Not available	
Explosion Data – Sensitivity to Mechanical Impact	:	Not available	
Explosion Data – Sensitivity to Static Discharge	:	Not available	
VOC Content	:	<40 g/L	

SECTION 10: STABILITY AND REACTIVITY

Reactivity:  Hazardous polymerization does not occur
Chemical Stability:  Stable under normal conditions.
Possibility of Hazardous Reactions:  Hazardous polymerization will not occur. 
Conditions to Avoid:  No information available. 
Incompatible Materials:  No materials to be especially mentioned.
Hazardous Decomposition Products: Carbon monoxide.  Carbon dioxide.  Hydrocarbons.
SECTION 11: TOXICOLOGICAL INFORMATION
Information on Toxicological Effects – Ingredient(s)
LD50 and LC50 Data
Asphalt (8052-42-4)		
LD50 Oral Rat	>5,000 mg/kg	
LD50 Dermal Rabbit	>2,000 mg/kg	

Carcinogenicity Data:		
Asphalt (8052-42-4)		
IARC Group	2B	
National Toxicity Program (NTP) Status	Twelfth Report – Items under consideration.	

SECTION 12: ECOLOGICAL INFORMATION
Toxicity – Ingredients
Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants.
Persistence and Degradability
No information available for this product.
Bioaccumulative Potential – Product
No information available for this product.
Bioaccumulative Potential – Ingredients
No information available for this product.
Mobility in Soil
No information available for this product.
Other Adverse Effects 

Other Information: Avoid release to the environment.

SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Recommendations: Dispose of in accordance with local, state, and federal regulations.

Additional Information: Empty containers should be taken for local recycling, recovery or waste disposal.
SECTION 14: TRANSPORT INFORMATION
In Accordance with DOT
Proper Shipping Name	:	Non-Regulated Material. 	
In Accordance with IMDG
Proper Shipping Name	:	Not Regulated.	
Hazard Class	:		
Identification Number	:		
Packing Group	:		
Marine Pollutant	:		

In Accordance with IATA
Proper Shipping Name	:	Not Regulated.	
Hazard Class	:		
Identification Number	:		
Packing Group	:		
Marine Pollutant	:		

In Accordance with TDG
Proper Shipping Name	:	Not Regulated.	
Hazard Class	:		
Identification Number	:		
Packing Group	:		
Marine Pollutant	:		

SECTION 15: REGULATORY INFORMATION
International Inventories

Chemical Name 	TSCA 	DSL 	NDSL 	EINECS	ELINCS 	ENCS 	CHINA 	KECL 	PICCS 	AICS 	
Petroleum Asphalt	X	X	-	X	-	-	X	X	X	X	
Stoddard Solvent	X	X	X	X	X	X	X	X	X	X	

TSCA 	Complies	
DSL 	Complies	
NDSL 	Complies	
EINECS	Complies	
ELINCS 	Complies	
ENCS 	Complies	
CHINA 	Complies	
KECL 	Complies	
PICCS 	Complies	
AICS 	Complies	

US Federal Regulations 
Asphalt (8052-42-4)	
Listed on the United States TSCA (Toxic Substances Control Act) Inventory	
	
Elastomeric Polymer (Proprietary)	
Listed on the United States TSCA (Toxic Substances Control Act) Inventory	
  US State Regulations
California Proposition 65
This product contains no known Proposition 65 chemicals.
State Right-to-Know
Chemical Name 	Massachusetts	New Jersey	Pennsylvania 	Illinois 	Rhode Island 	
Petroleum Asphalt	X	X	X		X	
Stoddard Solvent	X	X	X		X	
Canadian Regulations
Sentinel SB Dampproofing	
All components are listed in the WHMIS DSL.	
WHMIS Classification	Not classified.	

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Revision date		:	01/28/2022	
Other Information	:	This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200.	

Party Responsible for the Preparation of This Document
GMX, Inc.	
P.O. Box 743	
Matthews, NC 28106	

This information is based on our knowledge as of the Revision Date and is intended to describe the product only for the purposes of health, safety, and environmental requirements as of the Revision Date. It should not therefore be construed as guaranteeing any specific property of the product nor as providing any warranty, expressed or implied. The user assumes all responsibility, liability, risk of loss, damage, or expense arising out of, or in any way connected with, the handling, storage, use, or disposal of the product.

North America GHS US 2015 & WHMIS